第201回 | |
日時 | 平成11年7月7日(水)17:00より |
場所 | 東京工業大学理学部地球惑星科学教室会議室 石川台2号館315号室 |
講 演 者: | Ben Harte(エジンバラ大学地球科学科教授) |
講演題目: | Deep Mantle Mineral Inclusions in Diamonds from Sao Luiz, Brazil. |
An exceptional set of mineral inclusions in
diamonds from the Sao Luiz alluvial diamond deposit,
suggest derivation from both the lower mantle and the
relatively deep (sub-lithosphere) upper mantle. The upper
mantle suite is eclogitic in composition, and includes
both normal-Si and high-Si (majoritic) garnets together
with clinopyroxene. The majoritic garnets suggest depths
of origin of ca.250-400 kms, but may have been formed
initially at greater depths, because they show complex
reaction (exhumation?) textures. The lower mantle suite
of inclusions consists of: (Mg,Fe)O, (Mg,Fe)SiO3, CaSiO3, (Mg,Fe)3(Al,Fe)2Si3O12, and SiO2. The (Mg,Fe)SiO3
may be both low and high in Al2O3, and the (Mg,Fe)3(Al,Fe)2Si3O12,
is a tetra zonal phase with composition similar to
pyrope-almandine garnet and referred to as TAPP
(tetragonal almandine-pyrope phase). The associations of
minerals in one diamond and the mineral compositions
suggest the following mineral assemblages: ferropericlase
+ MgSi-perovskite(low-Al); ferropericlase +
MgSi-perovskite(low-Al) + TAPP; ferropericlase + SiO2; ferropericlase + MgSi-perovskite(high-Al).
It is presumed that CaSiO3, as the
principal Ca-bearing phase may accompany all of these
mineral assemblages, and that the assemblages represent a
range of expected peridotitic-eclogitic bulk
compositions. Comparison with experimental data, suggests
that the mineral assemblages have formed in the uppermost
part of the lower mantle at depths of ca. 660-800 kms,
and that it was here that they became trapped in
diamonds. Two distinctive features of composition are
also seen in the Sao Luiz lower mantle suite: (a) some
high-Fe (Fe/(Fe+Mg)>0.3)
ferropericlase-magnesiowustite inclusions; (b) the
occurrence of positive Eu anomalies in the CaSiO3 inclusions. These features may suggest
materials (protoliths) derived respectively from D” and
the crust, which have been convected and subducted to the
uppermost lower mantle, where encapsulation in diamond
occurred. Such features suggest the occurrence of layered
mantle convection. PAPER IN PRESS: Harte B, Harris, J.W., Hutchison, M.T., Watt, G.R. and Wilding, M.C. Lower, mantle mineral associations in diamonds from Sao Luiz, Brazil. In: Field Observations and High Pressure Experimentation: a Tribute to Francis R.(Joe) Boyd. (Fei, Y., Bertka, C.M. and Mysen, B.O., eds.) Geochemical Society Spec. Publ. No. 6 (1999). |